2-(4-Bromo­phen­yl)-4-(4-meth­oxy­phen­yl)-6,7,8,9-tetra­hydro-5H-cyclo­hepta­[b]pyridine

In the title compound, C₂₃H₂₂BrNO, the cyclo­heptane ring adopts a chair conformation. The pyridine ring makes dihedral angles of 58.63 (15) and 8.27 (16)° with the benzene rings. The dihedral angle between the benzene rings is 56.68 (17)°. The crystal packing features C—Br...π inter­actions [Br...centroid distances= 3.813 (2) and 3.839 (2) Å; C—Br...centroid = 126.25 (10) and 138.31 (10)°, respectively, forming a three dimensional supramolecular architecture.

2-[1-(4-Bromo­phen­yl)-3-hy­droxy-3-(4-meth­oxy­phen­yl)prop­yl]cyclo­hexa­nol

In the title compound, C₂₂H₂₇BrO₃, the cyclo­hexane ring adopts a chair conformation. The dihedral angle between the benzene rings is 41.9 (4)°. In the crystal, mol­ecules are linked by O—H...O and C—H...O hydrogen bonds, forming a three-dimensional network. In addition, π–π stacking inter­actions [centroid–centroid distance = 3.953 (6) Å] between the benzene rings of the meth­oxy­benzene groups occur.