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The structure of the title compound, [Cd(NCS)2(C7H9NO)2]n, consists of cadmium–thio­cyanate layers parallel to the ab plane. Pairs of CdII ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio­cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa­hedrally coordinated CdII ions occupied by the N atoms of two neutral 2-meth­oxy­aniline ligands. The crystal structure is stabilized by intra­layer N—H...S hydrogen bonds.

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In the ethyl­enedi­ammonium dication of the title salt, C2H10N22+·Cl·SCN, the N—C—C—N torsion angle is 72.09 (12)°. In the crystal, an extensive three-dimensional hydrogen-bonding network, formed by N—H...Cl and N—H...N hydrogen bonds, holds all the ions together.
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