metal-organic compounds
Open access
The structure of the title compound, [Cd(NCS)2(C7H9NO)2]n, consists of cadmium–thiocyanate layers parallel to the ab plane. Pairs of CdII ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thiocyanate groups, forming a two-dimensional network with the remaining two trans positions of the octahedrally coordinated CdII ions occupied by the N atoms of two neutral 2-methoxyaniline ligands. The crystal structure is stabilized by intralayer N—HS hydrogen bonds.
organic compounds
Open access
In the ethylenediammonium dication of the title salt, C2H10N22+·Cl−·SCN−, the N—C—C—N torsion angle is 72.09 (12)°. In the crystal, an extensive three-dimensional hydrogen-bonding network, formed by N—HCl and N—HN hydrogen bonds, holds all the ions together.