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The crystal structure of the title compound, C8H6FN3O, is stabilized by C—H...O hydrogen bonds, which link the mol­ecules into chains running parallel to the a axis.

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In the mol­ecule of the title compound, C9H9N3O, the angle formed by the least-squares line through the azide group with the normal to the plane of the benzene plane ring is 46.62 (16)°. The crystal structure features C—H...O hydrogen bonds, which link the mol­ecules into zigzag chains running parallel to [010].

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In the title compound, C8H6N4O3, the ketone [C—C(=O)—C] and nitro groups are tilted with respect to the benzene ring by 18.92 (6) and 24.11 (15)°, respectively. In the crystal, mol­ecules are linked into inter­woven chains running parallel to the [100] direction by C—H...N hydrogen bonds and weak π–π stacking inter­actions, with centroid–centroid separations of 3.897 (3) Å.
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