metal-organic compounds
Open access
The binuclear title complex, [Zn2(C22H28N3O)2(C3H9OSi)2], has a crystallographic imposed centre of symmetry. The ZnII atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenolate ligand and two bridging trimethylsilanolate anions in a distorted tetrahedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83 (5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858 (4):0.142 (4) and 0.665 (6):0.335 (6).
organic compounds
Open access
In the molecule of the title compound, C14H17NO2, the dihedral angle formed by the mean planes through the indan ring system and the aminopentenone fragment is 83.26 (13)°. An intramolecular N—HO hydrogen bond is observed. In the crystal, molecules are linked into one-dimensional chains extending along the [010] direction via O—HO and C—HO hydrogen bonds.
organic compounds
Open access
In the title compound, C14H13NOS, the dihedral angle formed by the mean planes through the indane ring system and the thiophene ring is 85.04 (11)°. The imine bond is located in the thiophene plane [the S—C—C—N torsion angle is 0.00 (3)°] and an intramolecular O—HN hydrogen bond is observed.