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The title compound, C12H18N82+·2NO3·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water mol­ecules are linked via O—H...N, N—H...O and O—H...O hydrogen bonds into a three-dimensional network.
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