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In the title compound, C9H10NO4+·Cl·2H2O, both the cation and the anion have crystallographic twofold rotation symmetry; in the former, one N and one C atom lie on the rotation axis. In the crystal structure, the ions and water mol­ecules are linked via O—H...O, O—H...Cl and N—H...Cl hydrogen bonds into layers parallel to (101).

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The six-membered ring in the title salt, C5H12NO+·Br, has a chair conformation. In the crystal, the cations are linked to the anions by N—H...Br hydrogen bonds.
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