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The structure of the title compound, C6H18N3·HPO4·H2PO4, is characterized by two kinds of inorganic chains running along the a-axis direction. The first one is composed of HPO42− anions, while the second one is built up by H2PO4 anions. Both types of chains are held together by O—H...O hydrogen bonds. The organic cations are attached to these chains through N—H...O and C—H...O hydrogen bonds. The piperazin-1,4-diium ring adopts a chair conformation.
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