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In the title compound, [Cu(C14H12N2)3](PF6)2·CH3CN, the [Cu(5,6-dmp)3]2+ cationic complex (5,6-dmp is 5,6-dimethyl-1,10-phenanthroline) is stabilized by two hexa­fluorido­phosphate anions and one acetonitrile solvent mol­ecule. The coordination geometry around the CuII atom can be described as distorted elongated octa­hedral with Rout = 2.277 (2) Å, Rin = 2.052 (2) Å and a tetra­gonality of 0.9011, acquiring a `static' stereochemistry. In the supra­molecular network, there are inter­molecular C—H...F and C—H...N inter­actions with R33(16), R22(7), R12(4), R33(16) and C32(7) motifs that lead to an infinite three-dimensional network.
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