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The title compound, Li3.5Eu1.5(MoO4)4, was prepared by solid-state reactions. The fundamental building units of the structure are LiO4 polyhedra (site symmetry \overline1), distorted LiO6 polyhedra and MoO4 tetra­hedra, which are further inter­connected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner.
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