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In the solid state, the title compound, C15H23NO4, forms centrosymmetric dimers in which individual mol­ecules are linked by intermolecular N—H...O hydrogen bonds. The pyrrole ring is planar within 0.004 (9) Å.

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The title compound, C21H32O4 crystallizes in a triclinic unit cell, which is very unusual for steroids. The asymmetric unit contains two independent mol­ecules with almost identical geometry, although they are slighly twisted in opposite directions. These mol­ecules form a dimer inter­connected via hydrogen bonds. Both mol­ecules have a cis A/B ring junction characteristic of a 5β-configuration, but differ in the orientation of their hydroxyl groups.

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In the title compound, C3H7NO2·NH4+·NO3-, the sarcosine zwitterions have an almost perfectly planar N-C-COO main chain and assemble in chains via hydrogen bonds. The ammonium and nitrate ions are arranged in sheets that alternate with sheets of sarcosine chains. The whole structure is stabilized by an extensive three-dimensional network of hydrogen bonds.

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The title compound, (C6H15N4O2)3·CrF6·3H2O, is isostructural with the vanadium analogue. One of the argininium cations is partially disordered over two different conformations. A complex network of N—H...O, N—H...F, O—H...O and O—H...F hydrogen bonds supports the structure.
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