journal menu
organic compounds
Open 
access
access
In the title compound, C12H14Cl2N2O2S, the molecule adopts a cis conformation with respect to the dichlorobenzoyl group against the thiono group about the C—N bond. However, the dichlorobenzene group and the thiourea moiety are twisted by 75.41 (8)°. An intramolecular N—H
O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O—HS and O—HO hydrogen bonds link the molecules, forming chains along the b-axis direction.
O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O—HS and O—HO hydrogen bonds link the molecules, forming chains along the b-axis direction.organic compoundsOpen access
access
In the title compound, C12H15FN2O2S, the molecule adopts a cis configuration of the fluorobenzoyl group with respect to the thiono group about their C—N bond. The dihedral angle between the fluorobenzoyl group and the thiourea N2CS fragment is 69.60 (11)°. An intramolecular N—HO hydrogen bond occurs. In the crystal, molecules form chains along the b-axis direction via O—HS and C—HO hydrogen bonds.
O hydrogen bond occurs. In the crystal, molecules form chains along the b-axis direction via O—HS and C—HO hydrogen bonds.organic compoundsOpen access
access
The title compound, C13H18N2O2S, adopts a cis conformation between the methylbenzoyl and thiono groups across their thiourea C—N bond. However, the methylbenzoyl group and N2CS thiourea moiety are twisted by 15.03 (3)°. In the molecule there is an N—HO hydrogen bond. In the crystal, molecules are linked by O—HO interactions, generating chains extending along the c-axis direction.
O hydrogen bond. In the crystal, molecules are linked by O—HO interactions, generating chains extending along the c-axis direction.organic compoundsOpen access
access
The two independent molecules in the asymmetric unit of the title compound, C11H12Cl2N2OS, exhibit different conformations, with the benzene ring and the N2CS thiourea group forming dihedral angles of 87.40 (18) and 69.42 (15)°. An intramolecular N—HO hydrogen bond is present in each molecule. Two further N—HO hydrogen bonds link the independent molecules into a dimer. In the crystal, the dimers are linked by N—HS and C—HS hydrogen bonds, forming chains parallel to the c axis.
O hydrogen bond is present in each molecule. Two further N—HO hydrogen bonds link the independent molecules into a dimer. In the crystal, the dimers are linked by N—HS and C—HS hydrogen bonds, forming chains parallel to the c axis.organic compoundsOpen access
access
The title compound, C10H10BrClN2OS, adopts a trans–cis conformation with respect to the position of the 3-chloropropanoyl and 4-bromophenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N2CS thiourea moiety. Intramolecular N—HO and C—HS hydrogen bonds occur. In the crystal, molecules are linked into chains along the c-axis direction by N—HS, C—HS and C—HO hydrogen bonds.
O and C—HS hydrogen bonds occur. In the crystal, molecules are linked into chains along the c-axis direction by N—HS, C—HS and C—HO hydrogen bonds.
