organic compounds
Open access
In the crystal structure of the title salt, C6H8N+·C7H5O3−, the anions and cations are linked by classical N—HO hydrogen bonds. The anions are connected by pairs of C—HO hydrogen bonds into inversion dimers and further linked by classical O—HO hydrogen bonds. Weak π–π interactions [centroid–centroid distances = 3.740 (3) and 3.855 (3) Å] also occur. The dihedral angle between the CO2− group and the benzene ring to which it is attached is 20.95 (8)°.
organic compounds
Open access
In the cation of the title compound, C14H13BrN+·C7H7O3S−, the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The molecular structure is stabilized by a weak intramolecular C—HO interactions. The crystal structure exhibits weak C—HO and π–π [centroid–centroid distance = 3.7466 (17) Å] interactions, forming a three dimensional network.
organic compounds
Open access
In the title salt, C8H12N+·C7H5O3−, the cation is disordered over two orientations with site occupancies of 0.565 (7) and 0.435 (7). In the anion, the carboxylate group makes the dihedral angle of 4.19 (18)° with the benzene ring. In the crystal, the ions are connected by N—HO and O—HO hydrogen bonds, forming a three-dimensional network.