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In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothio­amide group is 75.1 (2)°. In the crystal, the main mol­ecule is linked to the solvent mol­ecule by a weak N—H...N hydrogen bond while O—H...S hydrogen bonds link the mol­ecules into columns along [100].

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In the title compound, [Pd(C11H13N3O2S)(C18H15P)]·C2H5OH, the PdII atom is tetra­coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio­semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri­phenyl­phosphane group. The five-membered ring adopts a distorted envelope conformation with PdII as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth­oxy­phenyl group is fused to the six-membered ring. Weak C—H...O inter­actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing.
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