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The title compound, C7H4BrNO, crystallizes with two mol­ecules in the asymmetric unit. The two molecules exhibit nearly linear C—C[triple bond]N nitrile bond angles of 179.1 (4) and 177.1 (4)°. In the crystal, the mol­ecules are linked into a one-dimensional hydrogen-bonded chain by inter­actions between the phenol H atom and the nitrile N atom [N...O = 2.805 (4) and 2.810 (4) Å].
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