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In the solid state, the structure of the title compound, C18H15N5, is stabilized by weak C—H...N interactions. Mol­ecules are arranged in layers parallel to the bc plane forming an inter­esting supra­molecular structure.

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In the title compound, C18H14N4O, the mol­ecules are disordered about a crystallographic twofold axis, leading to 50:50 disorder of the O- and N-atom sites within the oxazole ring. As a consequence, symmetry-related oxazole C-N and C-O bonds are averaged. The oxazole ring makes a dihedral angle of 6.920 (1)° with the pyridyl ring in the 2-position and 60.960 (2)° with the pyridyl rings in the 4- and 5-positions.

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In the title compound, C10H20O4, the dioxane ring adopts a chair conformation. The tert-butyl group occupies an equatorial position, and is staggered with respect to the O atoms of the dioxane ring. In the crystal, mol­ecules are connected by O—H...O hydrogen-bonds into zigzag chains of R44(8) and R22(12) ring motifs that run parallel to the a axis.
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