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The title compound, C17H16O5, was prepared through a cyclization reaction of 2-(3',4',5-trimeth­oxy­biphenyl-2-yl­oxy)acetyl chloride. The two benzene rings form a dihedral angle of 34.55 (5)°. The crystal structure does not feature any hydrogen bonds.

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The title compound, C13H10N4O2S, was prepared through a cyclization reaction of 1,10-phenanthroline-5,6-dione and thio­urea. The dihedral angle between the pyridine rings is 8.22 (2)°. In the crystal, mol­ecules are connected by N—H...O, O—H...N, N—H...S and O—H...S hydrogen bonds, forming a three-dimensional network.

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The title compound, C15H13NO2, was prepared through a palladium-catalysed Suzuki-Miyaura coupling reaction. The dihedral angle between the biphenyl rings is 40.96 (6)°. The meth­oxy groups are twisted slightly out of the plane of the benzene ring [C-C-C-C torsion angles = -3.61 (18) and 12.6 (2)°]. The packing of the molecules is stabilized by van der Waals inter­actions.

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The title compound, C14H13NO4, was prepared through a palladium-catalysed Suzuki-Miyaura coupling reaction. The asymmetric unit comprises two mol­ecules related by pseudo-inversion symmetry. The dihedral angles between the benzene rings in the two mol­ecules are 44.30 (6) and 48.50 (6)° while those between the benzene ring and the nitro group are 6.54 (13) and 5.73 (10)°. The crystal packing is defined only by Van der Waals inter­actions.
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