metal-organic compounds
The title compound has a fivefold interpenetrating diamondoid three-dimensional metal-organic framework, with each ZnII centre surrounded by two O-donor atoms from monodentate carboxylate groups belonging to two different benzene-1,4-diacetate ligands and by two triazole N-donor atoms from two different 1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene ligands.
research papers
A cadmium(II) complex, prepared by reaction of Cd(NO3)2·6H2O with terephthalic acid and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene in H2O, possesses a three-dimensional framework with 3,8-connected three-dimensional binodal {4.52}2{42.510.612.7.83} topology. The compound exhibits a strong fluorescence emission in the solid state at room temperature.
research papers
A one-dimensional cyanide-bridged coordination polymer has been synthesized by the reaction of Tb(NO3)3·6H2O with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen) and Cs3[Mo(CN)8]·4H2O at room temperature. X-ray diffraction analysis reveals that the compound consists of one-dimensional chains in which [Tb(tmphen)2(DMF)(H2O)]3+ and [MoV(CN)8]3- units are linked in an alternating fashion through bridging cyanide ligands. Magnetic investigations show that ferromagnetic interactions exist in the compound.