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In the title compound, {[Tb(C12H8NO2)3(H2O)2]·H2O}n, the TbIII cation is in an eight-coordinate environment, ligated by six carboxyl­ate O atoms from five 3-(pyridin-4-yl)benzoate (L) ligands and by two O atoms from water mol­ecules. The cations are bridged by the carboxyl­ate O atoms of the L ligands to form a two-stranded polymeric chain which is assembled into a three-dimensional supra­molecular network through regular inter­chain O-H...N hydrogen bonding. On excitation at 320 nm, the title compound displays a series of emissions, which were assigned to the characteristic electronic transitions of TbIII.
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