Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ²N,O}copper(II)

In the centrosymmetric mononuclear title complex, [Cu(C₁₈H₂₀N₂O₂)₂], the Cu^II atom is four-coordinated in a trans-CuN₂O₂ square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl­benzene and 2,4-dimethyl­benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intra­molecular C—H...N hydrogen bond occurs.

N-(2,2-Dimethyl­propano­yl)-N′-(2-meth­oxy­phen­yl)thio­urea

In the title compound, C₁₃H₁₈N₂O₂S, the carbonyl­thio­urea fragment is nearly planar with an r.m.s. deviation of 0.0096 Å. The dihedral angle between carbonyl­thio­urea group and the benzene ring is 19.16 (16)°. There are two intra­molecular N—H...O hydrogen bonds, which lead to two pseudo-six-membered rings. Weak intra­molecular C—H...S hydrogen bonding also occurs.