2-[(4-Bromo­phenyl­imino)­meth­yl]-4,6-di­iodo­phenol

The title compound, C₁₃H₈BrI₂NO, was prepared by the reaction of 3,5-diiodo­salicyl­aldehyde with 4-bromo­phenyl­amine in ethanol. There is an intra­molecular O—H...N hydrogen bond in the mol­ecule, which generates an S(6) ring. The dihedral angle between the benzene rings is 2.6 (3)°.

2-[(2-Chloro­phen­yl)imino­meth­yl]-4,6-di­iodo­phenol

The asymmetric unit of the title compound, C₁₃H₈ClI₂NO, contains half of the mol­ecule situated on a mirror plane. The hy­droxy group is involved in the formation of an intra­molecular O—H...N hydrogen bond. π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.629 (3) Å] form stacks along the b axis. In the crystal, weak C—H...O and C—H...Cl inter­actions are observed.