metal-organic compounds
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The asymmetric unit of the title complex, [Pb(C8H5O4)(C9H6NO)]n, comprises a PbII cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the PbII atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electrons, and is based on a Ψ-dodecahedron. The quinolin-8-olate is chelating and the 3-carboxybenzoate anion forms bonds to four different PbII atoms. The benzoate end of the 3-carboxybenzoate ligand chelates one PbII atom and simultaneously bridges two PbII atoms on either side, forming a chain along the b axis. The carboxyl end of the 3-carboxybenzoate connects to a neighbouring chain by employing its carbonyl atom to form a bond to a PbII atom and the hydroxyl group to form a hydrogen bond to a quinolin-8-olate O atom. Thereby, a layer is formed in the bc plane.
metal-organic compounds
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The asymmetric unit of the title compound, {[Pb(C9H6NO)2]·0.5C3H7NO}n, comprises Pb(quinolate)2 and half a dimethylformamide molecule (which is disordered about a centre of inversion). The quinolate ligands N,O-chelate to a PbII ion and simultaneously bridge a neighbouring PbII ion to form a polymeric chain along [100] comprising Pb-linked Pb2O2 distorted rhombi. These chains pack to form a square grid, with the channels thus defined occupied by the disordered solvent molecules.
metal-organic compounds
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The complete molecule of the title complex, [Cu2(C13H19N2O2)2(N3)2], is generated by the application of a centre of inversion. The central Cu2N2 core is a rhombus as the μ2-azide ligands bridge in an asymmetric fashion. Each CuII atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anticipated oxide O, imine N and amine N atoms. The resulting N4O coordination geometry is based on a square pyramid. No specific intermolecular interactions are noted in the crystal packing, but the amine H atoms form intramolecular N—HO(oxide)/N(azide) hydrogen bonds.
metal-organic compounds
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Two distinct coordination geometries are found in the binuclear title complex, [Ni2(C13H19N2O2)2(N3)2(CH3OH)], as one Schiff base ligand is pentadentate, coordinating via the anticipated oxide O, imine N and amine N atoms (as for the second, tridentate, ligand) but the oxide O is bridging and coordination also occurs through the methoxy O atom. The NiII atoms are linked by a μ2-oxide atom and one end of a μ2-azide ligand, forming an Ni2ON core. The coordination geometry for the NiII atom coordinated by the tridentate ligand is completed by the methoxy O atom derived from the pentadentate ligand, with the resulting N3O3 donor set defining a fac octahedron. The second NiII atom has its cis-octahedral N4O2 coordination geometry completed by the imine N and amine N atoms of the pentadentate Schiff base ligand, a terminally coordinated azide N and a methanol O atom. The arrangement is stabilized by an intramolecular hydrogen bond between the methanol H and the oxide O atom. Linear supramolecular chains along the a axis are formed in the crystal packing whereby two amine H atoms from different amine atoms hydrogen bond to the terminal N atom of the monodentate azide ligand.