Di-μ-oxido-bis­({2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphen­olato}titanium(IV)) chloro­form disolvate

In the title structure, [Ti₂(C₁₆H₁₆N₂O₂)₂O₂]·2CHCl₃, the Ti atom is coordinated in a distorted octa­hedral geometry by the O,N,N′,O′ donor set of the salalen ligand and by two μ₂-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti₂(μ₂-O)₂ fragment, the metal–oxygen distances are significantly different [1.7962 (19) and 1.9292 (19) Å]. In the crystal, the chloro­form mol­ecule is anchored via an N—H...Cl and a bifurcated C—H...(O,O) hydrogen bond. Slipped π–π stacking [shortest C...C distance = 3.585 (4) Å] and C—H...π inter­actions contribute to the coherence of the structure.