organic compounds
Open access
In the title compound, C10H11N3O2S, the 1,3-benzodioxole and hydrazinecarbothioamide fragments are nearly planar [(mean deviations from planarity for non-H atoms of 0.0325 (12) Å and 0.0707 (10) Å, respectively] and subtend a dihedral angle of 29.06 (5)°. In the crystal, molecules are linked by pairs of almost linear N—HS hydrogen bonds, forming inversion dimers. These dimers are additionally connected by weaker and strongly bent N—HS interactions into chains along [101]. There is one additional weak N—HO contact which, if considered as an interaction, leads to the formation of a three-dimensional network.