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In the title compound, C8H7N3O2S, the dihedral angle between the thia­zol and isoxazole rings is 34.08 (13)°. In the crystal, the mol­ecules are linked by pairs of N—H...N hydrogen bonds, forming inversion dimers, and C—H...O inter­actions, resulting in chains along the b-axis direction.

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In the title compound, C18H16N4, the dihedral angle between the benzene and phenyl rings is 61.40 (4)°. In the crystal, mol­ecules are linked by N—H...N(nitrile) hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H...N(amine) hydrogen bonds, and both units are arranged almost perpendicular to each other [angle between dimer mean planes = 84.43 (12)°]. This arrangement is extended to form a ladder-like structure parallel to the c axis.
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