organic compounds
Open access
In the title compound, C14H8Cl2N4O2, the pyrazine rings are orthogonal to the benzene ring, making dihedral angles of 88.42 (8) and 89.22 (8)°. The Cl atoms attached to the pyrazine rings deviate by −0.0597 (5) and 0.0009 (5) Å from the ring plane. The crystal structure features C—HN hydrogen bonds.
organic compounds
Open access
In the title compound, C16H10Cl2N4O4, the pyrazine rings make dihedral angles of 67.82 (9) and 75.91 (9)° with the benzene ring, while the dihedral angle between the pyrazine rings is 44.69 (10)°. The methoxycarbonyl group makes a dihedral angle of 16.82 (8)° with the benzene ring to which it is attached. In the crystal, C—HO hydrogen bonds link the molecules, forming chains running along the ab plane.
organic compounds
Open access
The asymmetric unit of the title compound, C16H10N2O2, contains one half-molecule, the complete molecule being generated by twofold rotation symmetry. The plane of the pyrazine ring forms a dihedral angle of 64.87 (6)° with that of the benzene ring, and the planes of the two benzene rings are inclined to one another by 54.20 (6)°. The O atom deviates from the plane of the benzene ring by 0.1549 (8) Å. There are no significant intermolecular interactions in the crystal.
organic compounds
Open access
The asymmetric unit of the title compound, C14H8Cl2N4O2, contains one half-molecule, the complete molecule being generated by the operation of a twofold rotation axis. The Cl atom deviates significantly from the plane of the pyrazine ring [0.0215 (4) Å]. The central benzene ring makes a dihedral angle of 72.82 (7)° with the plane of the pyrazine ring.