organic compounds
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In the title salt, C21H21Cl2N2O2+·NO3−, the imidazole ring makes dihedral angles of 43.39 (14) and 10.9 (2)° with the 4-methylphenyl and 2,4-dichlorophenyl rings, respectively. The molecule adopts a Z conformation about the C=C double bond, which links the imidazole ring to the 4-methylphenoxy unit via an ethoxy chain. In the crystal, cations and anions are linked into chains by N—HO and C—HO hydrogen bonds.
metal-organic compounds
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The dinuclear title complex, [Co2(C15H8O7)2(H2O)6], lies across an inversion center. The unique CoII ion is coordinated in a slightly distorted octahedral coordination geometry by two O atoms from a chelating 4-(carboxyphenoxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxylate group of a symmetry-related 4-(carboxyphenoxy)phthalate ligand. In the crystal, O—HO hydrogen bonds link the molecules into a three-dimensional network.
metal-organic compounds
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The title compound, [Zn(CH3CO2)Cl(C14H14N4)]n, is a one-dimensional coordination polymer in which the ZnII ion is tetrahedrally coordinated by two N atoms of a bridging 1,1′-[1,4-phenylenebis(methylene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the ZnII ion gives an infinite one-dimensional zigzag structure along the b-axis direction with the charge balanced by the chloride and acetate ions.
organic compounds
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In the title molecule, C37H48O4S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1 (1)°. The hydroxy group is involved in a weak intramolecular O—HOsulfonate hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682 (17):0.318 (17) ratio. In the crystal, weak C—HO hydrogen bonds link the molecules into columns in direction [100].
organic compounds
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The asymmetric unit of the title compound, C17H24O2, contains two independent molecules with different conformations. The least-squares plane through the cyclohexane ring makes dihedral angles of 52.9 (5) and 81.4 (4)° with the benzene ring in the two molecules. The cyclohexane ring adopts a chair conformation in both molecules. In the crystal, weak C—HO hydrogen bonds link molecules related by translation in [100] into two crystallographically independent chains.
organic compounds
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In the title compound, C13H13NO3, the isoxazole ring is approximately coplanar with the phenyl ring, the dihedral angle between their planes being 7.37 (19)°. In the crystal, centrosymmetrically related molecules are linked into dimers by pairs of C—HO hydrogen bonds, generating a ring of graph-set motif R22(10).
organic compounds
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In the title salt, C7H8N3+·BF4−, the 1,2,4-triazolo[4,3-a]pyridinium cation is planar [maximum deviation of 0.016 (2) Å for all non-H atoms]. The cation and anion constitute a tight ionic pair with an FN [2.911 (4) Å] intermolecular attractive interaction. The ionic pairs form dimers via stacking interactions between inversion-related cations, the normal distance between the cation planes being 3.376 (5) Å. The dimers are packed in stacks along the a axis and linked via C—HF hydrogen bond, forming a three-dimensional network.