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In title compound, C8H8F3NO, the meth­oxy group is inclined at 8.7 (4)° to the benzene ring plane. The crystal structure is stabilized by inter­molecular N—H...F, N—H...N and C—H...F hydrogen-bonding inter­actions.

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The title mol­ecule, C5H4ClN3O2, possesses mirror symmetry, with all of the atoms lying in the mirror plane. There is an intra­molecular N—H...O hydrogen bond involving the adjacent –NO2 and –NH2 groups. A short C—H...O inter­action is also observed. In the crystal, adjacent mol­ecules are linked via N—H...Cl and N—H...N hydrogen bonds, forming chains propagating along [100].
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