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In the acid mol­ecule of the title complex, C10H8N2·C8H8O3, the acetyl C—C—C—O torsion angle is −32.1 (3)°, and in the mol­ecule of the base, the dihedral angle between the two pyridine rings is 23.41 (10)°. In the crystal structure, inter­molecular O—H...N hydrogen bonds link the acid and the base mol­ecules into a one-dimensional triple-helix framework extended along the b axis.
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