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In the title complex, [Mn(C6H4NO2S)2(C12H8N2)] or [MnL2(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central MnII atom is coordinated by two carboxylic O atoms and two thiol­ate S atoms of two L ligands and two N atoms from one phen mol­ecule, giving a distorted octa­hedral geometry. The pyridyl H atoms form strong N—H...O hydrogen bonds with the carbonyl O atoms of the adjacent mol­ecules, generating a chain structure propagating in [100].
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