Acta Crystallographica Section B
Acta Crystallographica
Section B
STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS
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Acta Cryst.
(2012).
B
68
,
266-274
https://doi.org/10.1107/S0108768112011226
Download PDF of article
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Phase transition at high pressure in Cu
2
CO
3
(OH)
2
related to the reduction of the Jahn-Teller effect
M. Merlini
,
N. Perchiazzi
,
M. Hanfland
and
A. Bossak
Malachite, Cu
2
CO
3
(OH)
2
, transforms directly into a rosasite structure at high pressure as a result of the pressure-induced reduction of the Jahn-Teller distortion of CuO
6
coordination polyhedra.
Keywords:
high pressure
;
first-order transition
;
malachite
;
Jahn-Teller effect
.
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