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In the title compound, C17H21N2O6P·CH3OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H...O, N—H...O and C—H...O hydrogen bonds link the α-amino­phospho­nic acid and methanol mol­ecules into chains that propagate parallel to the a axis.
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