metal-organic compounds
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In the title complex, [FeIIFeIII2(C9H10BN6)2(CN)6(CH3OH)4]·2CH3OH, two [FeIII(Tp)(CN)3]− anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4]2+ cation, forming a centrosymmetric trinuclear unit. These units are connected via O—HO and O—HN hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.