organic compounds
Open access
In the molecule of the title compound, C20H18O4, the dihedral angle between the naphthalene ring system and the benzene ring is 81.74 (5)°. An intermolecular C—HO interaction is formed between an H atom at the 6-position of the naphthalene ring and the O atom of the methoxy group at the 7-position.
organic compounds
Open access
In the molecule of the title compound, C32H24O5, the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost antiparallel. The two benzene rings make a dihedral angle of 21.18 (10)°, and are inclined to the naphthalene ring system by 86.53 (9) and 82.95 (8)°, respectively. In the crystal, C—HO interactions are observed involving aromatic and methoxy H atoms with ketonic carbonyl O atoms, as well as C—Hπ interactions between aromatic H atoms and the π-systems of naphthalene and benzene rings. These interactions form a three-dimensional architecture and afford a waved alignment of the naphthalene ring systems along the c axis.
organic compounds
Open access
In the title molecule, C25H20O4, the naphthalene and phenoxy groups are oriented nearly perpendicular with respect to the benzene ring of the benzoyl group, with dihedral angles of 89.61 (5) and 86.13 (6)°, respectively. The crystal structure features C—HO and C—Hπ interactions.