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In the centrosymmetric binuclear title compound, [Cu2(C7H5O2)4(C7H9N)2], the CuII atom is coordinated by four O atoms from benzoate anions and one N atom from a dimethyl­pyridine ligand. A paddle-wheel-like dimer is formed by two CuII ions and four benzoate anions with two 3,5-dimethyl­pyridine ligands at the axial position of the CuII ions. The dihedral angle between the two unique benzene rings is 84.26 (16)°. The dihedral angles between the pyridine ring and the benzene rings are 61.67 (15) and 34.27 (14)°. There is π–π stacking of inversion-related pyridine rings, with a centroid–centroid distance of 3.833 (2) Å.

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The title compound, C17H21BrN4OS, was synthesized as a potential reverse transcriptase (RT) inhibitor of the human immunodeficiency virus type 1 (HIV-1). In the molecule, there is an N—H...S hydrogen bond making a five-membered ring. In the crystal, mol­ecules are connected into centrosymmetric dimers via pairs of N—H...N and weak C—H...N hydrogen bonds. The crystal structure also features C—H...O inter­actions.
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