Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Acta Cryst. (2012). B68, 40-56
https://doi.org/10.1107/S0108768111053298

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Structural phase transition to disorder low-temperature phase in [Fe(ptz)₆](BF₄)₂ spin-crossover compounds

J. Kusz, M. Zubko, R. B. Neder and P. Gütlich

In the spin-crossover compound [Fe(ptz)₆](BF₄)₂ six different phases are observed. The low-spin disordered phase was solved in a novel approach to accommodate the very unusual twinning.

Keywords: spin crossover; phase transition; disorder; iron(II).

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Structural phase transition to disorder low-temperature phase in [Fe(ptz)6](BF4)2 spin-crossover compounds

Structural phase transition to disorder low-temperature phase in [Fe(ptz)₆](BF₄)₂ spin-crossover compounds