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The title tetranuclear organotin compound has a core of three fused Sn2O2 rings. The bulk of the molecule is planar, with the n-butyl and 2-(2-methoxyethoxy)ethyl chains extending perpendicular to the plane.

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The title novel noncentrosymmetric metal-organic framework was prepared solvothermally using the tetra­dentate linker tetra­kis­[(imidazol-1-yl)methyl]methane (tiym) in the presence of zinc nitrate under acidic conditions. With its four peripheral imidazole N atoms, the tiym linkers are bridged by four [ZnCl2] subunits to generate a three-dimensional diamond topological framework.
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