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In the title compound, [FeCl2(C18H15P)2], the Fe atom exhibits a distorted tetra­hedral coordination involving two Cl-ions and two P donor functions of the triphenyl­phosphine ligands, with angles P-Fe-P = 111.25 (3)° and Cl-Fe-Cl = 124.42 (4)°.

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The title compound, [Mn2Br4(C15H13N3)2], is the first crystallographically characterized metal complex of the N-(8-quinol­yl)-o-phenyl­ene­diamine ligand. The centre of the mol­ecule lies on a crystallographic inversion centre, so the Mn2(μ-Br)2 four-membered ring is planar with Mn—Br bond lengths of 2.6210 (5) and 2.7147 (6) Å.
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