metal-organic compounds
The title compound, [Ni2(C3H2O4)2(C4H4N2)(H2O)2]n, has been prepared from the hydrothermal reaction of nickel(II) chloride, malonic acid and pyrazine. The NiII atoms are linked via coordinated malonates, forming a two-dimensional network with cavities of 6.14 × 5.60 Å. These sheet structures are further connected into a three-dimensional network by bridging pyrazine ligands which have inversion symmetry, the mean distance between the layers being 7.39 Å. The coordination geometry around the NiII atom is a tetragonally elongated octahedron, with pyrazine N and aqua O atoms at the apical positions.