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The title compound, C5H11NO5S, has been obtained by reacting 2-meth­yl-2-nitro­propanol with methane­sulfon­yl chloride. The average S=O and S—O bond lengths are 1.414 (3) and 1.570 (3) Å, respectively. The mol­ecules are linked via C—H...O inter­actions, forming a three-dimensional network.
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