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The title compound, [Cd(C6H4NO2)2]n, is a two-dimensional coordination polymer, which consists of CdII atoms and bridging nicotinate anions. The Cd atom is coordinated in a highly distorted CdO4N2 octahedron by two chelating carboxyl­ate groups and two cis pyridyl groups.

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The title compound, C15H11ClO2, was synthesized from 3-(3-chloro­phenyl)-1-(2-hydroxy­phenyl)­prop-2-en-1-one. The pyrone ring adopts a half-chair conformation.

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Pyridine-3-carboxylic acid (nicH) reacts with iron(II) chloride tetra­hydrate in a methanol–water mixture to form the title compound, [Fe(C6H4NO2)2(H2O)4]. The FeII atom is in a slightly distorted octa­hedral coordination. The crystal structure is stabilized by O—H...O hydrogen bonds involving all the water H atoms and the carboxyl­ate groups.
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