organic compounds
The title compound, C20H10Cl2N2O2, is an industrially important red pigment. The molecule has inversion symmetry. The molecule is not entirely planar, as shown by the dihedral angle of 176.7 (3)° between the planes of the benzene ring at the center and that at the extremity. The molecules are stacked in a `hunter's fence' fashion (i.e. when viewed from the side, the molecules cross one another with an angle of about 50° in a grid-like structure) along the a axis.
organic compounds
The title compound, C20H10Cl2N2S2·2C3H7NO, is a dimethylformamide (DMF) disolvate of DTQ-Cl, which is a thionated pigment derivative of 2,9-dichloroquinacridone. The DTQ-Cl molecule is centrosymmetric and entirely planar. Two DMF molecules are hydrogen-bonded to DTQ-Cl, through the NH group of DTQ-Cl and the O atom of DMF. The molecular plane of DMF is twisted with respect to the skeleton of DTQ-Cl by 21.4 (1)°.
organic compounds
The title compound, C20H10Cl2N2S2·2C4H9NO, is a dimethylacetamide (DMA) disolvate of DTQ-Cl, which is a thionated derivative of a 2,9-dichloroquinacridone pigment. The compound shows polymorphism and this paper reports the monoclinic form (space group P21/c, Z = 4). Two DMA molecules are hydrogen bonded via their O atoms to the NH group of DTQ-Cl. The molecular planes of the two DMA molecules are asymmetrically twisted with respect to the DTQ-Cl skeleton by 11.65 (8) and 31.58 (9)°.
organic compounds
The title compound, C20H10Cl2N2S2·2C4H9NO, is a dimethylacetamide (DMA) disolvate of DTQ-Cl, which is a thionated derivative of a 2,9-dichloroquinacridone pigment. The compound shows polymorphism and this paper reports the triclinic form (space group P, Z = 1). The DTQ-Cl molecule is centrosymmetric and planar, while the DMA molecule is orientationally disordered. Two symmetry-related DMA molecules are hydrogen bonded via their O atoms to the NH groups of DTQ-Cl. The molecular plane of DMA is twisted with respect to the DTQ-Cl skeleton by 73.6 (1)°.
organic compounds
The title compound, C20H10Cl2N2O2, is one of the quinacridone derivatives known as a red pigment. The molecule has inversion symmetry. The quinacridone molecules are connected by bifurcated N—HO hydrogen bonds along [110] to form a two-dimensional hydrogen-bond network.