organic compounds
The molecule of the title compound, C21H22N2O2, is nearly planar, except for the C(CH3)2 group on the cyclohexene ring. Molecules are connected via electrostatic CO contacts, forming zigzag pseudo-chains along the c axis.
organic compounds
The title compound, 4-phenylpyridinium-3-squarate, C15H9NO3, exhibits an interplanar angle between the pyridinium and squarate rings of 0.6 (1)°. It displays a dipolar electronic ground-state structure, with a positively charged pyridinium fragment and a negatively charged squarate moiety. In the molecule, the two aromatic rings are twisted by 31.6 (1)°. The bond lengths within the squarate system represent average values for the two possible resonance structures, with a central typical carbonyl bond [1.203 (2) Å] flanked by two longer `semicarbonyl' bonds of lengths 1.228 (2) and 1.221 (2) Å.
organic compounds
The title compound, 2C9H8NO2+·C4O42−, contains a dianion with approximately D4h symmetry [C—C = 1.465 (4)–1.470 (4) Å and C—O = 1.248 (4)–1.264 (4) Å]. Individual dianions are linked to four neighbouring 8-hydroxyquinolinium cations by OH—N [2.666 (4) and 2.681 (4) Å] and OH—O [2.596 (3) and 2.605 (3) Å] hydrogen bonds to generate a polymeric chain.
organic compounds
The title compound (systematic name: 6α-acetoxy-4,5α-epoxy-3-methoxy-17-methyl-morphin-7-ene), C20H23NO4, crystallizes with one molecule in the asymmetric unit. The molecular structure exhibits features typical of morphine derivatives with a T configuration. The three-dimensional packing is stabilized by intermolecular C—HN and C—Hπ interactions.
organic compounds
Cations of the title compound, 1-carbamoyl-2-(4-hydroxyphenyl)ethylammonium chloride monohydrate, C9H13N2O2+·Cl−·H2O, are connected by intermolecular N—HO [NO = 2.905 (3) Å] hydrogen bonds between the amide and 4-hydroxy functions into helical chains propagating along the [010] axis. The Cl− ions and water O atom participate in a complex pattern of hydrogen bonds to link these ribbons into a three-dimensional network.
organic compounds
Cations of the title compound, C3H9N2O+·C4HO4−·H2O, are connected by intermolecular Nammonium—HOamide hydrogen bonds into helical chains propagating in the [010] direction. These chains are further linked by Nammonium—HO hydrogen bonds to the hydrogensquarate anions, which in turn form O—HO-bridged chains in the [100] direction, thereby giving rise to a three-dimensional network. The water O atoms participate in two O—HO hydrogen bonds to the anions and one OH—Namide bridge to the cation.