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The title complex, [Ag4(C5F6O4)2(C14H8N2)(C4H8O)2]n, exhibits a one-dimensional chain structure propagated through inversion centres, with two crystallographically independent AgI atoms in the asymmetric unit. One of the Ag atoms has a distorted trigonal-pyramidal coordination, defined by two carboxyl O atoms from two hexafluoro­glutarate (HFG2−) anions, one N atom from 4,4′-biphenyl­dicarbonitrile and one apical O atom of tetrahydro­furan. The other Ag atom is coordinated by two O atoms from two HFG2− anions.
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