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organic compounds
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The conformation of the title compound, C27H34O, is stabilized by a weak intramolecular C—H
π interaction. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclohexane rings in classical chair conformations, with C—C—C angles in the range 107.75 (10)–111.35 (9)°. Although the molecule contains a hydroxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed in the crystal structure.
π interaction. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclohexane rings in classical chair conformations, with C—C—C angles in the range 107.75 (10)–111.35 (9)°. Although the molecule contains a hydroxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed in the crystal structure.organic compoundsOpen access
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In the molecule of the title compound, C25H24FN, the dihedral angle between the best planes of the quinoline fragment (rings A and B) and the benzene ring (C) is 9.51 (4)°. In the crystal, molecules are linked into centrosymmetric dimers via pairs of weak C—HF interactions. The molecules are stacked into chains along the a axis by weak off-set π–π interactions between the A and C rings of translation-related molecules with a centroid–centroid distance of 3.6440 (2) Å.
F interactions. The molecules are stacked into chains along the a axis by weak off-set π–π interactions between the A and C rings of translation-related molecules with a centroid–centroid distance of 3.6440 (2) Å.
