organic compounds
Open access
The title compound, C13H20O3S5, is bisected by a crystallographic twofold rotation axis, which relates the two halves of the molecule to one another: one S, one C and one O atom lie on the axis. The thione S atom lies in the plane of the five-membered rings with an r.m.s. deviation of 0.0042 (5) Å. Parts of the 17-membered macrocycle were refined using a two-part disorder model [occupancies of 0.553 (14) and 0.447 (14)]. There are no noteworthy intermolecular interactions.
organic compounds
Open access
In the title compound, C16H16N2O3S6, the two five-membered rings form a dihedral angle of 7.86 (9)°. Weak C—HN hydrogen bonds link the molecules to form a chain along c; the chains are further connected by weak C—HO hydrogen bonds to form a three-dimensional supramolecular network.