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The title compound, [Zn(C12H27O3SSi)2(C7H9N)], is a mol­ecular zinc thiol­ate containing, as an additional ligand, 3,5-dimethyl­pyridine. The ZnII ion coordination is distorted trigonal-bipyramidal, formed by two S, two O and one N atom, with the Zn atom lying on a twofold rotation axis. Mol­ecules pack as discrete units, with no inter­molecular contacts shorter than those arising from van der Waals forces.
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