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In the title complex, [Sn(C6H6)3(C12H15N2S2)], the Sn atom is in a distorted tetra­hedral configuration.

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The title compound, [Bi(C5H10NS2)2I(C12H8N2)], is monomeric, with the Bi atom chelated by the S atoms of two N,N-diethyl­dithio­carbamate ligands and the N atoms of 1,10-phenanthroline. An iodo ligand completes the coordination, with the seven-coordinate Bi atom adopting a highly distorted capped octa­hedral geometry.
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