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The title compound, [Cu(C7H4O5S)(C12H8N2)(H2O)2]·H2O, contains a monomeric zwitterion in which the CuII atom displays a square-pyramidal geometry defined by two N atoms of one 1,10-phenanthroline, one O atom from the carboxylate group of the 3-sulfonatobenzoate, and two O atoms from two water mol­ecules. Extensive O—H...O inter­molecular hydrogen bonds generate a two-dimensional network, enhancing the stability of the structure.

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In the title compound, [CuCl(C10H8N2)2](C7H5O5S)·3H2O, the CuII ion is coordinated by two 2,2-bipyridine and one chloro ligand in a trigonal–bipyramidal geometry. A hydrogen-bonding network consolidates the crystal structure.
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