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The title complex, [Yb(C9H12)(C26H42N2)Cl] or {(2,6-Pri2C6H3)NC(CH3)}2CH](tBuC5H4)YbCl, exists as a monomeric mol­ecule; the six-membered chelate ring adopts a boat conformation. The Yb atom is six-coordinate and the shape of the mol­ecule approximates to a three-legged piano stool.
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