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The title two-dimensional coordination polymer, {[Ag(C6H8N2)2]PF6}n, has been formed by the self-assembly of 4-amino­methyl­pyridine (amp) ligands with silver(I) hexa­fluoro­phosphate in a 2:1 ratio. The polymer consists of dimeric silver–amp rectangles that are linked together to make a larger hexa­metallic recta­ngle.
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